What is the embrittlement resistance of 309S stainless steel sheet?
As a supplier of 309S stainless steel sheets, I often encounter inquiries from customers regarding the various properties of this material, especially its embrittlement resistance. Embrittlement resistance is a crucial characteristic that determines the performance and longevity of stainless steel sheets in different applications. In this blog, I will delve into the concept of embrittlement resistance in 309S stainless steel sheets, exploring its significance, influencing factors, and how it compares to other stainless steel grades.
Understanding Embrittlement in Stainless Steel
Embrittlement refers to the loss of ductility and toughness in a material, making it more prone to cracking and failure under stress. In stainless steels, embrittlement can occur due to several mechanisms, including carbide precipitation, sigma phase formation, and hydrogen embrittlement. These processes can significantly reduce the material's ability to deform plastically and absorb energy, leading to sudden and catastrophic failures.
Carbide precipitation is one of the most common causes of embrittlement in stainless steels. When stainless steel is heated in the temperature range of 425 - 870°C (800 - 1600°F), chromium carbides can form at the grain boundaries. This depletes the surrounding area of chromium, reducing its corrosion resistance and making the material more susceptible to intergranular corrosion and cracking.
Sigma phase formation is another factor that can contribute to embrittlement. Sigma phase is an intermetallic compound that forms at intermediate temperatures (550 - 800°C or 1020 - 1470°F) in stainless steels containing ferrite. Sigma phase is hard and brittle, and its presence can reduce the ductility and toughness of the material.
Hydrogen embrittlement occurs when hydrogen atoms diffuse into the stainless steel lattice. This can happen during welding, pickling, or in environments containing hydrogen gas. Hydrogen atoms can interact with dislocations and grain boundaries, causing them to become more brittle and prone to cracking.
Embrittlement Resistance of 309S Stainless Steel Sheet
309S stainless steel is an austenitic stainless steel with a high chromium and nickel content. The high chromium content provides excellent corrosion resistance, while the nickel content enhances the material's ductility and toughness. These properties make 309S stainless steel highly resistant to embrittlement compared to other stainless steel grades.
One of the key factors contributing to the embrittlement resistance of 309S stainless steel is its low carbon content. The "S" in 309S stands for "low carbon," which means that the carbon content is limited to a maximum of 0.08%. This reduces the risk of carbide precipitation at the grain boundaries, minimizing the potential for intergranular corrosion and embrittlement.
In addition to its low carbon content, 309S stainless steel has a fully austenitic microstructure. Austenite is a face-centered cubic (FCC) crystal structure that is inherently ductile and tough. Unlike ferrite, austenite does not form sigma phase at intermediate temperatures, which further enhances the material's embrittlement resistance.
The high nickel content in 309S stainless steel also plays a crucial role in its embrittlement resistance. Nickel is a strong austenite stabilizer, which helps to maintain the austenitic microstructure even under high-stress conditions. This improves the material's ability to deform plastically and absorb energy, reducing the risk of cracking and failure.


Comparison with Other Stainless Steel Grades
When comparing the embrittlement resistance of 309S stainless steel sheet with other stainless steel grades, it is important to consider the specific application and environmental conditions. For example, 316 Steel Plate Stainless is another popular austenitic stainless steel grade that is known for its excellent corrosion resistance. However, 316 stainless steel has a lower chromium and nickel content compared to 309S stainless steel, which may make it more susceptible to embrittlement under certain conditions.
SS 304 Stainless Steel is also a widely used austenitic stainless steel grade. While 304 stainless steel has good corrosion resistance and ductility, it has a lower nickel content than 309S stainless steel. This may result in reduced embrittlement resistance, especially in high-temperature applications.
Stainless Steel Plate Sus304 is a Japanese equivalent of 304 stainless steel. Similar to 304 stainless steel, Sus304 may have lower embrittlement resistance compared to 309S stainless steel due to its lower nickel content.
Applications of 309S Stainless Steel Sheet
The excellent embrittlement resistance of 309S stainless steel sheet makes it suitable for a wide range of applications, especially those involving high temperatures and corrosive environments. Some common applications of 309S stainless steel sheet include:
- Welding applications: 309S stainless steel is often used as a filler metal for welding other stainless steel grades. Its high chromium and nickel content provide good corrosion resistance and mechanical properties, while its low carbon content minimizes the risk of carbide precipitation and embrittlement.
- Heat exchangers: In heat exchanger applications, 309S stainless steel sheet can withstand high temperatures and corrosive fluids without losing its ductility and toughness. This ensures reliable performance and long service life.
- Furnace components: 309S stainless steel is commonly used in furnace components such as heating elements, muffles, and radiant tubes. Its high-temperature resistance and embrittlement resistance make it suitable for these demanding applications.
- Chemical processing equipment: The excellent corrosion resistance and embrittlement resistance of 309S stainless steel make it ideal for use in chemical processing equipment, such as reactors, tanks, and pipelines.
Conclusion
In conclusion, the embrittlement resistance of 309S stainless steel sheet is a result of its low carbon content, fully austenitic microstructure, and high nickel content. These properties make 309S stainless steel highly resistant to carbide precipitation, sigma phase formation, and hydrogen embrittlement, ensuring reliable performance and long service life in a variety of applications.
If you are looking for a high-quality stainless steel sheet with excellent embrittlement resistance, 309S stainless steel is an excellent choice. As a supplier of 309S stainless steel sheets, I am committed to providing our customers with the best products and services. If you have any questions or would like to discuss your specific requirements, please feel free to contact me for procurement and negotiation.
References
- ASM Handbook, Volume 3: Alloy Phase Diagrams, ASM International, 1992.
- Stainless Steel: A Guide to Selection and Application, The Nickel Institute, 2008.
- Welding Metallurgy and Weldability of Stainless Steels, John C. Lippold and David J. Kotecki, Wiley, 2005.




